Just to be clear here the NAS 2.0 has a 2TB Logical Volume limit but the Volume Group can be up to 16TB. So are you only seeing 2TB as the volume group or for the logical volume?
Also you never stated what is the RAID controller and model type.
I saw this KB from 3Ware and being that it is a 9500 series you may want to try to enable the Auto Carving to see if you will see the 2 seperate arrays then you can add them together in the disk manager. I was thinking there would be an option for LBA 64bit mode but not an expert on the old controllers.