This means the first drive has the Operating System and you cannot do anything else with that first drive.
You could just buy a small flash USB drive and make that your boot volume and then make a raid 1 or buy more drives and make a raid 10.
If your array controller has some good utilities, you should be able to present the Array as Logical Volumes. I have not yet been successful at this myself.
I also strongly suggest against a raid-0. If one drive fails, you lose everything.